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acetone azine : ウィキペディア英語版
acetone azine

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Acetone azine is the simplest ketazine. It is an intermediate in some hydrazine manufacturing processes.
== Synthesis ==

Acetone azine can be prepared from acetone and hydrazine:
:2 (CH3)2CO + N2H4 → 2 H2O + ()2
It can also be produced from acetone (2 eq.), ammonia (2 eq.) and hydrogen peroxide (1 eq.).〔. 〕 The first step is the formation of acetone imine, Me2C=NH; this is then oxidized by hydrogen peroxide through a complex mechanism to give 3,3-dimethyloxaziridine, which reacts with a further molecule of ammonia to produce acetone hydrazone. The hydrazone then condenses with a further molecule of acetone to produce the azine. The acetone azine product is distilled out of the reaction mixture as its azeotrope with water (''n''(H2O)/''n''(azine) ≈ 6).

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